Ball end mills are useful when a part has curved, sculpted, or intersecting surfaces. Their rounded tips can follow a mold cavity, machine a fillet, or blend a sloped wall into a floor. They are commonly used on aluminum, carbon and stainless steels, and titanium, with suitable tooling, speeds, and chip control. Plastics and graphite can also be machined, though heat, brittleness, or dust may call for different cutting conditions. The material alone does not determine the result; machine rigidity and toolpath matter too.
On 3D surfaces, the ball’s contact point shifts as the cutter moves. A small stepover can leave finer scallops, but it increases machining time. A larger stepover removes stock faster and may leave visible ridges that need finishing. Ball end mills suit detailed contours better than broad, flat areas, where a flat-bottom cutter may be more efficient. They are not always ideal. I would avoid assuming a smooth-looking toolpath guarantees a smooth part; runout, tool wear, and vibration can still mark the surface.
Tips: Match stepover to the finish you need, then inspect a test cut under angled light. Keep the tool engaged smoothly, and check for chip buildup in deep cavities. A little trial and error is normal.